Issue 36, 2006
From the journal:

Chemical Communications

A single-bonded cationic terminal borylene complex

Dragoslav Vidovic,a   Michael Findlater,a   Gregor Reeskea  and  Alan H. Cowley*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas, USA
E-mail: cowley@mail.utexas.edu
Fax: (+1) 512-471-6822
Tel: (+1) 512-471-7484

Abstract

The cationic terminal borylene complex [(η5-C5H5)(CO)2FeB(η5-C5Me5)][AlCl4] has been isolated from the reaction of [(η5-C5H5)(CO)2FeB(Cl)(η1-C5Me5)] with AlCl3 and on the basis of X-ray crystallographic data, spectroscopic data and a DFT calculation it is concluded that the B→Fe bond order is one.

Graphical abstract: A single-bonded cationic terminal borylene complex

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Article information

DOI
https://doi.org/10.1039/B609475A
Article type
Communication
Submitted
07 Jul 2006
Accepted
22 Jul 2006
First published
08 Aug 2006

Chem. Commun., 2006, 3786-3787

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A single-bonded cationic terminal borylene complex

D. Vidovic, M. Findlater, G. Reeske and A. H. Cowley, Chem. Commun., 2006, 3786 DOI: 10.1039/B609475A

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