Issue 34, 2006
From the journal:

Chemical Communications

Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid†

Jun Mo,a   Lijin Xu,a   Jiwu Ruan,a   Shifang Liua  and  Jianliang Xiao*a  

* Corresponding authors

a Liverpool Center for Materials and Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UK
E-mail: j.xiao@liv.ac.uk
Fax: +44 151-7943589
Tel: +44 151-7942937

Abstract

In contrast to almost all of the known examples of Heck arylation of unsaturated alcohols, which yield predominately β-arylated products, arylation under the Pd-DPPP catalysis in ionic liquid leads preferentially to aryl substitution at the α carbon, providing an easy pathway to this valuable class of olefins.

Graphical abstract: Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B608033B
Article type
Communication
Submitted
06 Jun 2006
Accepted
13 Jul 2006
First published
07 Aug 2006

Chem. Commun., 2006, 3591-3593

Permissions

Request permissions

Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid

J. Mo, L. Xu, J. Ruan, S. Liu and J. Xiao, Chem. Commun., 2006, 3591 DOI: 10.1039/B608033B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements