Issue 33, 2006

Chiral (iminophosphoranyl)ferrocenes: highly efficient ligands for rhodium- and iridium-catalyzed enantioselective hydrogenation of unfunctionalized olefins

Abstract

A series of chiral (iminophosphoranyl)ferrocenes (1–3) are highly efficient ligands for Rh- and Ir-catalyzed hydrogenation of a number of unfunctionalized olefins; almost perfect enantiomeric excesses (up to 99% ee) have been achieved under mild reaction conditions.

Graphical abstract: Chiral (iminophosphoranyl)ferrocenes: highly efficient ligands for rhodium- and iridium-catalyzed enantioselective hydrogenation of unfunctionalized olefins

Article information

Article type
Communication
Submitted
26 May 2006
Accepted
27 Jun 2006
First published
17 Jul 2006

Chem. Commun., 2006, 3537-3539

Chiral (iminophosphoranyl)ferrocenes: highly efficient ligands for rhodium- and iridium-catalyzed enantioselective hydrogenation of unfunctionalized olefins

T. T. Co and T. Kim, Chem. Commun., 2006, 3537 DOI: 10.1039/B607450B

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