On a novel coordination mode of phosphinine C5H5P

Christoph Elschenbroich; Jörg Six; Klaus Harms

doi:10.1039/B606739E

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On a novel coordination mode of phosphinine C₅H₅P†‡

Christoph Elschenbroich,*^a Jörg Six^a and Klaus Harms^a

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* Corresponding authors

^a Fachbereich Chemie, Philipps-Universität Marburg, Germany
E-mail: eb@chemie.uni-marburg.de
Fax: +49 6421 2825653
Tel: +49 6421 2825527

Abstract

In an unprecedented coordination mode two phosphinines simultaneously bridge a Mn–Mn bond and the latter with two Mn(CO)₃ fragments; the distortion of the resulting central heterobicyclo[1.1.0]butane unit follows from the Mn(18VE) requirement.

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Supplementary files

Crystal structure data TXT (63K)

Article information

DOI: https://doi.org/10.1039/B606739E
Article type: Communication
Submitted: 12 May 2006
Accepted: 05 Jun 2006
First published: 06 Jul 2006

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Chem. Commun., 2006, 3429-3431

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On a novel coordination mode of phosphinine C₅H₅P

C. Elschenbroich, J. Six and K. Harms, Chem. Commun., 2006, 3429 DOI: 10.1039/B606739E

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