Issue 30, 2006

Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph˙ radical

Abstract

The kinetics and energetics of the reversible reaction of phenols with the dpph˙ radical have been studied; steric shielding of the divalent N by the o-NO2 in dpph˙ seems to be the main cause of the entropic barriers of this reaction.

Graphical abstract: Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph˙ radical

Article information

Article type
Communication
Submitted
05 May 2006
Accepted
07 Jun 2006
First published
27 Jun 2006

Chem. Commun., 2006, 3252-3254

Kinetic and thermodynamic parameters for the equilibrium reactions of phenols with the dpph˙ radical

M. C. Foti and C. Daquino, Chem. Commun., 2006, 3252 DOI: 10.1039/B606322E

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