Issue 31, 2006
From the journal:

Chemical Communications

Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines†

Lawrence A. Vanderark,a   Timothy J. Clark,a   Eric Rivard,a   Ian Manners,*b   J. Chris Slootwegc  and  Koop Lammertsma*c  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Canada

b School of Chemistry, University of Bristol, Bristol, UK
E-mail: Ian.Manners@bristol.ac.uk
Fax: +44 (0)117 9290509
Tel: +44 (0)117 9287650

c Department of Chemistry, Faculty of Science, Vrije Universiteit, De Boelelaan 1084, The Netherlands
E-mail: k.lammertsma@few.vu.nl

Abstract

A strained 1-phenyl-2,3-dimethylphosphirene undergoes anionic ring-opening polymerization upon initiation with n-butyl lithium at ambient temperature to yield polyvinylenephosphine, an unsaturated organophosphorus polymer.

Graphical abstract: Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

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Article information

DOI
https://doi.org/10.1039/B606311J
Article type
Communication
Submitted
03 May 2006
Accepted
07 Jun 2006
First published
29 Jun 2006

Chem. Commun., 2006, 3332-3333

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Anionic ring-opening polymerization of a strained phosphirene: A route to polyvinylenephosphines

L. A. Vanderark, T. J. Clark, E. Rivard, I. Manners, J. C. Slootweg and K. Lammertsma, Chem. Commun., 2006, 3332 DOI: 10.1039/B606311J

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