Issue 30, 2006
From the journal:

Chemical Communications

Easy access to stable pentavalent uranyl complexes†

Jean-Claude Berthet,*a   Gérald Siffredi,a   Pierre Thuérya  and  Michel Ephritikhinea  

* Corresponding authors

a Service de Chimie Moléculaire, DSM, DRECAM, CNRS URA 331, CEA Saclay, France
E-mail: berthet@drecam.cea.fr, ephri@drecam.cea.fr
Fax: +33 (0)169086640
Tel: +33 (0)169086042

Abstract

Reaction of UO2I2(THF)3 with 1 molar equivalent of KC5R5 (R = H, Me) in pyridine led to the uranyl(V) compound {[UO2(Py)5][KI2(Py)2]}∞, which is an infinite 1D polymer in its crystalline form; the UO2X(THF)n (X = I, OSO2CF3) complexes were obtained by reduction of their U(VI) parents with TlC5H5 or KC5R5 in THF.

Graphical abstract: Easy access to stable pentavalent uranyl complexes

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Article information

DOI
https://doi.org/10.1039/B605710A
Article type
Communication
Submitted
21 Apr 2006
Accepted
01 Jun 2006
First published
19 Jun 2006

Chem. Commun., 2006, 3184-3186

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Easy access to stable pentavalent uranyl complexes

J. Berthet, G. Siffredi, P. Thuéry and M. Ephritikhine, Chem. Commun., 2006, 3184 DOI: 10.1039/B605710A

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