Elucidation of the bonding in Mn(η2-SiH) complexes by charge density analysis and T1 NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

Wolfgang Scherer; Georg Eickerling; Maxim Tafipolsky; G. Sean McGrady; Peter Sirsch; Nicholas P. Chatterton

doi:10.1039/B604843A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Elucidation of the bonding in Mn(η²-SiH) complexes by charge density analysis and T₁ NMR measurements: asymmetric oxidative addition and anomeric effects at silicon†

Wolfgang Scherer,*^a Georg Eickerling,^a Maxim Tafipolsky,^a G. Sean McGrady,*^b Peter Sirsch^b and Nicholas P. Chatterton^c

Author affiliations

* Corresponding authors

^a Lehrstuhl für Chemische Physik und Materialwissenschaften, Universität Augsburg, Augsburg, Germany
E-mail: wolfgang.scherer@physik.uni-augsburg.de
Fax: +49 0821 598 3227
Tel: +49 0821 598 3350

^b Department of Chemistry, University of New Brunswick, Fredericton, N.B., Canada
E-mail: smcgrady@unb.ca

^c Department of Chemistry, University of Sheffield, Sheffield, UK

Abstract

The bonding in Mn(η²-SiH) complexes is interpreted in terms of an asymmetric oxidative addition whose extent is controlled by the substitution pattern at the hypercoordinate silicon centre, and especially by the ligand trans to the η²-coordinating SiH moiety.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/B604843A
Article type: Communication
Submitted: 12 Apr 2006
Accepted: 17 May 2006
First published: 07 Jun 2006

Download Citation

Chem. Commun., 2006, 2986-2988

Permissions

Request permissions

Elucidation of the bonding in Mn(η²-SiH) complexes by charge density analysis and T₁ NMR measurements: asymmetric oxidative addition and anomeric effects at silicon

W. Scherer, G. Eickerling, M. Tafipolsky, G. S. McGrady, P. Sirsch and N. P. Chatterton, Chem. Commun., 2006, 2986 DOI: 10.1039/B604843A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications