Issue 22, 2006
From the journal:

Chemical Communications

Hosomi–Sakurai reactions of silacyclic allyl silanes†

Jonathan D. Sellars,a   Patrick G. Steel*a  and  Michael J. Turnera  

* Corresponding authors

a Department of Chemistry, University of Durham, Science Laboratories, South Road, Durham, UK
E-mail: p.g.steel@durham.ac.uk
Fax: +44 (0)191 384 4737
Tel: +44 (0)191 334 2131

Abstract

Substituted silacyclohexenes, generated through silene–diene [4 + 2] cycloaddition reactions, undergo Lewis acid promoted Sakurai type reactions with acetals to afford, following oxidation of the resultant fluorosilane, 1,4-diols with four contiguous chiral centres.

Graphical abstract: Hosomi–Sakurai reactions of silacyclic allyl silanes

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Article information

DOI
https://doi.org/10.1039/B602642G
Article type
Communication
Submitted
22 Feb 2006
Accepted
11 Apr 2006
First published
02 May 2006

Chem. Commun., 2006, 2385-2387

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Hosomi–Sakurai reactions of silacyclic allyl silanes

J. D. Sellars, P. G. Steel and M. J. Turner, Chem. Commun., 2006, 2385 DOI: 10.1039/B602642G

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