Issue 15, 2006
From the journal:

Chemical Communications

Diplatinum alkynyl chromophores as sensitisers for lanthanide luminescence in Pt2Ln2 and Pt2Ln4 (Ln = Eu, Nd, Yb) arrays with acetylide-functionalized bipyridine/phenanthroline†

Hai-Bing Xu,a   Lin-Xi Shi,a   En Ma,a   Li-Yi Zhang,a   Qiao-Hua Weia  and  Zhong-Ning Chen*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, China
E-mail: czn@ms.fjirsm.ac.cn

Abstract

Incorporation of diplatinum complex Pt2(μ-dppm)2(bpyC[triple bond, length as m-dash]C)4 or Pt2(μ-dppm)2(phenC[triple bond, length as m-dash]C)4 with Ln(hfac)3(H2O)2 (Ln = Nd, Eu, Yb) gave a series of Pt2Ln2 and Pt2Ln4 bimetallic arrays, in which the excitation of d(Pt) → π*(R–C[triple bond, length as m-dash]C) MLCT absorption induces sensitisation of lanthanide luminescence through efficient d → f energy transfer from PtII alkynyl chromophores.

Graphical abstract: Diplatinum alkynyl chromophores as sensitisers for lanthanide luminescence in Pt2Ln2 and Pt2Ln4 (Ln = Eu, Nd, Yb) arrays with acetylide-functionalized bipyridine/phenanthroline

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Article information

DOI
https://doi.org/10.1039/B602222G
Article type
Communication
Submitted
14 Feb 2006
Accepted
01 Mar 2006
First published
15 Mar 2006

Chem. Commun., 2006, 1601-1603

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Diplatinum alkynyl chromophores as sensitisers for lanthanide luminescence in Pt2Ln2 and Pt2Ln4 (Ln = Eu, Nd, Yb) arrays with acetylide-functionalized bipyridine/phenanthroline

H. Xu, L. Shi, E. Ma, L. Zhang, Q. Wei and Z. Chen, Chem. Commun., 2006, 1601 DOI: 10.1039/B602222G

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