Issue 20, 2006

Bond length and bond multiplicity: σ-bond prevents short π-bonds

Abstract

Analysis of model compounds such as Fe2(CO)6, C2 and HBBH shows that π-bonds left to themselves are shorter than σ-bonds; in many ways σ-bonds prevent π-bonds from adopting their optimal shorter distances.

Graphical abstract: Bond length and bond multiplicity: σ-bond prevents short π-bonds

Supplementary files

Article information

Article type
Communication
Submitted
13 Feb 2006
Accepted
29 Mar 2006
First published
18 Apr 2006

Chem. Commun., 2006, 2164-2166

Bond length and bond multiplicity: σ-bond prevents short π-bonds

E. D. Jemmis, B. Pathak, R. B. King and H. F. Schaefer III, Chem. Commun., 2006, 2164 DOI: 10.1039/B602116F

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