Issue 18, 2006
From the journal:

Chemical Communications

This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications†

Georgios Bokolinis,a   T. Riis-Johannessen,b   Lindsay P. Harding,a   John. C. Jeffery,b   Neil McLaya  and  Craig R. Rice*a  

* Corresponding authors

a Department of Chemical and Biological Sciences, University of Huddersfield, Huddersfield
E-mail: c.r.rice@hud.ac.uk
Fax: (+44)148-447-2182

b School of Chemistry, University of Bristol, Cantocks Close, Bristol

Abstract

The ligand L1 forms a dinuclear double helicate with Cu+ but upon addition of Ba2+ to the system a side-by-side species is formed both in solution and in the solid state; in the presence of Na+ both the helicate and the side-by-side species are formed in roughly equal amounts in solution.

Graphical abstract: This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications

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Article information

DOI
https://doi.org/10.1039/B600597G
Article type
Communication
Submitted
16 Jan 2006
Accepted
20 Mar 2006
First published
03 Apr 2006

Chem. Commun., 2006, 1980-1982

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This facile interconversion of dinuclear double helicates and side-by-side species: a reprogrammable ligand with potential sensor applications

G. Bokolinis, T. Riis-Johannessen, L. P. Harding, John. C. Jeffery, N. McLay and C. R. Rice, Chem. Commun., 2006, 1980 DOI: 10.1039/B600597G

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