Issue 27, 2006
From the journal:

Chemical Communications

Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}†

Anupama Ranganathan,a   Abdelkrim El-Ghayoury,a   Cécile Mézière,a   Etienne Harté,b   Rodolphe Cléracb  and  Patrick Batail*a  

* Corresponding authors

a Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers, UMR 6200 CNRS-Université d'Angers, 2 Boulevard Lavoisier, 49045 Angers, France
E-mail: patrick.batail@univ-angers.fr
Fax: +33 241 735 011

b Centre de Recherches Paul Pascal (CRPP-CNRS), UPR 8641, 115 Avenue Dr. Schweitzer, 33600 Pessac, France

Abstract

The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic–inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.

Graphical abstract: Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

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Article information

DOI
https://doi.org/10.1039/B600159A
Article type
Communication
Submitted
06 Jan 2006
Accepted
26 May 2006
First published
08 Jun 2006

Chem. Commun., 2006, 2878-2880

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Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}

A. Ranganathan, A. El-Ghayoury, C. Mézière, E. Harté, R. Clérac and P. Batail, Chem. Commun., 2006, 2878 DOI: 10.1039/B600159A

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