Issue 12, 2006
From the journal:

Chemical Communications

A structurally characterized Ni–Al methyl-bridged complex with catalytic ethylene oligomerization activity†

Zhiqiang Weng,ab   Shihui Teo,a   Lip Lin Kohb  and  T. S. Andy Hor*b  

* Corresponding authors

a Institute of Chemical and Engineering Sciences, No. 1, Pesek Road, Jurong Island, Singapore

b Department of Chemistry, National University of Singapore, 3 Science Drive 3, Kent Ridge, Singapore
E-mail: andyhor@nus.edu.sg
Fax: (+65) 6873 1324

Abstract

A bimetallic Ni–Al (2.5087(15) Å) complex with an agostic α-C–H, [η-C5H4CH[double bond, length as m-dash]N(C6F5)]Fe[η-C5H4PPh2]Ni(AlMe3), has been isolated and crystallographically established. The complex is active towards ethylene oligomerization/polymerization under moderate conditions.

Graphical abstract: A structurally characterized Ni–Al methyl-bridged complex with catalytic ethylene oligomerization activity

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Article information

DOI
https://doi.org/10.1039/B517824J
Article type
Communication
Submitted
16 Dec 2005
Accepted
24 Jan 2006
First published
15 Feb 2006

Chem. Commun., 2006, 1319-1321

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A structurally characterized Ni–Al methyl-bridged complex with catalytic ethylene oligomerization activity

Z. Weng, S. Teo, L. L. Koh and T. S. A. Hor, Chem. Commun., 2006, 1319 DOI: 10.1039/B517824J

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