Issue 12, 2006
From the journal:

Chemical Communications

Phthalocyanine-modulated isomerization behaviour of an azo-based photoswitch†

José L. Rodríguez-Redondo,a   Ángela Sastre-Santos,a   Fernando Fernández-Lázaro,*a   Dilcelli Soares,b   Gianluca C. Azzellini,*b   Bevan Elliottc  and  Luis Echegoyen*c  

* Corresponding authors

a División de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, Avda. del Ferrocarril s/n, Elche 03202, Spain
E-mail: fdofdez@umh.es
Fax: +34-966658351
Tel: +34-966658405

b Departamento de Química Fundamental, Universidade de São Paulo, Av. Prof. Lineu Prestes 748, São Paulo SP 05508-900, Brazil
E-mail: gcazzell@iq.usp.br

c Department of Chemistry, Clemson University, 219 Hunter Laboratories, Clemson, SC 29634, USA
E-mail: luis@clemson.edu

Abstract

A photoswitchable azobenzene–phthalocyanine–azobenzene triad has been synthesized and its electrochemical properties determined. Energy transfer among the subunits allows for modification of the E–Z ratio by selective excitation of the phthalocyanine moiety.

Graphical abstract: Phthalocyanine-modulated isomerization behaviour of an azo-based photoswitch

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Article information

DOI
https://doi.org/10.1039/B517518F
Article type
Communication
Submitted
12 Dec 2005
Accepted
20 Jan 2006
First published
09 Feb 2006

Chem. Commun., 2006, 1265-1267

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Phthalocyanine-modulated isomerization behaviour of an azo-based photoswitch

J. L. Rodríguez-Redondo, Á. Sastre-Santos, F. Fernández-Lázaro, D. Soares, G. C. Azzellini, B. Elliott and L. Echegoyen, Chem. Commun., 2006, 1265 DOI: 10.1039/B517518F

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