Issue 12, 2006
From the journal:

Chemical Communications

Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

Hee-Yoon Lee,*a   Suyoung Ryu,a   Hongkyu Kang,a   Young-wook Junb  and  Jinwoo Cheon*b  

* Corresponding authors

a Center for Molecular Design and Synthesis, Department of Chemistry, KAIST, Daejon, Korea
E-mail: leehy@kaist.ac.kr
Fax: 8242 869 8370
Tel: 8242 869 2835

b Department of Chemistry, Yonsei University, Seoul, Korea
E-mail: jcheon@yonsei.ac.kr
Fax: 8223647050
Tel: 82221235631

Abstract

Remarkable selectivity is achieved in the cleavage of benzyl ethers using ball-shaped palladium nanocatalysts, Pd@MCM-48, in an MCM-48 matrix. The unique nanocatalysts not only feature unprecedented complete hydrogenolysis selectivity of a benzyl ether over hydrogenation of a double bond, but also demonstrate selective cleavage of unsubstituted benzyl ether over substituted benzyl ethers.

Graphical abstract: Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

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Article information

DOI
https://doi.org/10.1039/B517082F
Article type
Communication
Submitted
02 Dec 2005
Accepted
30 Jan 2006
First published
16 Feb 2006

Chem. Commun., 2006, 1325-1327

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Selective catalytic activity of ball-shaped Pd@MCM-48 nanocatalysts

H. Lee, S. Ryu, H. Kang, Y. Jun and J. Cheon, Chem. Commun., 2006, 1325 DOI: 10.1039/B517082F

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