Issue 15, 2006
From the journal:

Chemical Communications

A new chalcogenide homologous series A2[M5+nSe9+n] (A = Rb, Cs; M = Bi, Ag, Cd)

Jun-Ho Kim,a   Duck-Young Chunga  and  Mercouri G. Kanatzidis*a  

* Corresponding authors

a Department of Chemistry, Michigan State University, East Lansing, USA
E-mail: kanatzidis@chemistry.msu.edu

Abstract

The ternary and quaternary selenides, β-CsBi3Se5, Rb2CdBi6Se11, CsAg0.5Bi3.5Se6, CsCdBi3Se6, Rb2Ag1.5Bi7.5Se13, and Cs2Ag1.5Bi7.5Se13, are all members of the new homologous series A2[M5+nSe9+n] and crystallize in structures related to each other in a systematic way; these compounds are mid gap semiconductors and are of interest as thermoelectric materials.

Graphical abstract: A new chalcogenide homologous series A2[M5+nSe9+n] (A = Rb, Cs; M = Bi, Ag, Cd)

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Article information

DOI
https://doi.org/10.1039/B516790F
Article type
Communication
Submitted
28 Nov 2005
Accepted
10 Feb 2006
First published
07 Mar 2006

Chem. Commun., 2006, 1628-1630

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A new chalcogenide homologous series A2[M5+nSe9+n] (A = Rb, Cs; M = Bi, Ag, Cd)

J. Kim, D. Chung and M. G. Kanatzidis, Chem. Commun., 2006, 1628 DOI: 10.1039/B516790F

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