Issue 11, 2006

An experimental electron density study on “1-zirconacyclopent-3-yne”

Abstract

An electron density analysis of the 1-zirconacyclopent-3-yne complex has been carried out based on X-ray diffraction data, showing that the coordination mode of the but-2-yne-1,4-diyl ligand to the metal is a resonance hybrid between η2-σ, σ-coordination, as the major contributor, and η4-π, π-coordination.

Graphical abstract: An experimental electron density study on “1-zirconacyclopent-3-yne”

Supplementary files

Article information

Article type
Communication
Submitted
15 Nov 2005
Accepted
13 Jan 2006
First published
03 Feb 2006

Chem. Commun., 2006, 1233-1235

An experimental electron density study on “1-zirconacyclopent-3-yne”

D. Hashizume, N. Suzuki and T. Chihara, Chem. Commun., 2006, 1233 DOI: 10.1039/B516229G

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