Issue 9, 2006
From the journal:

Chemical Communications

Photooxidation of Co-thiolato complexes in protic and aprotic solvents†

Billy Hernandez,a   Yanju Wang,a   Dong Zhanga  and  Matthias Selke*a  

* Corresponding authors

a Department of Chemistry & Biochemistry, California State University, Los Angeles, Los Angeles, CA, USA
E-mail: mselke@calstatela.edu
Fax: +1 (323) 343 6490
Tel: +1 (323) 343 2347

Abstract

Protic solvents decrease the susceptibility of the thiolate ligand in Co(III) thiolato complexes toward attack by singlet oxygen, but greatly increase the conversion of the peroxidic intermediate to the sulfenato product.

Graphical abstract: Photooxidation of Co-thiolato complexes in protic and aprotic solvents

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Article information

DOI
https://doi.org/10.1039/B514601A
Article type
Communication
Submitted
14 Oct 2005
Accepted
19 Dec 2005
First published
20 Jan 2006

Chem. Commun., 2006, 997-999

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Photooxidation of Co-thiolato complexes in protic and aprotic solvents

B. Hernandez, Y. Wang, D. Zhang and M. Selke, Chem. Commun., 2006, 997 DOI: 10.1039/B514601A

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