Issue 10, 2006
From the journal:

Chemical Communications

Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]+

Ngon T. Tran,a   Jay R. Stork,a   David Pham,a   Marilyn M. Olmstead,a   James C. Fettingera  and  Alan L. Balch*a  

* Corresponding authors

a Department of Chemistry, University of California, One Shields Avenue, Davis, CA, USA
E-mail: albalch@ucdavis.edu
Fax: +1 (530) 752 8995
Tel: +1 (530) 752 0941

Abstract

Trimeric green [(i-PrNC)12RhI3]Cl3·4.5H2O, monomeric [(C6H11NC)4RhI](BPh4) and [(i-PrNC)4RhI](BPh4) (both yellow), and red, dimeric [(C6H11NC)8RhI2]Cl2·0.5C6H6·2H2O have been crystallized.

Graphical abstract: Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]+

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Article information

DOI
https://doi.org/10.1039/B513700D
Article type
Communication
Submitted
26 Sep 2005
Accepted
11 Jan 2006
First published
25 Jan 2006

Chem. Commun., 2006, 1130-1132

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Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]+

N. T. Tran, J. R. Stork, D. Pham, M. M. Olmstead, J. C. Fettinger and A. L. Balch, Chem. Commun., 2006, 1130 DOI: 10.1039/B513700D

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