Bi-isoquinoline can be used as a building block to prepare a new family of non-sterically hindering chelates, including a macrocyclic system; the endocyclic nature of the ligands has been confirmed by the X-ray structure of an octahedral tris-chelate iron(II) complex, which shows that the three chelates are easily accommodated in the coordination sphere of the metal in spite of their crescent shape.
F. Durola, J. Sauvage and O. S. Wenger, Chem. Commun., 2006, 171 DOI: 10.1039/B513222C
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