Issue 3, 2006

Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase

Abstract

The binuclear [Ni(L)Fe(CO)3], 1, and trinuclear [Ni(L){Fe(CO)3}2], 2, complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via μ2-S bridging modes, C[double bond, length as m-dash]N imine π-bonds and potential Ni–Fe bonding interactions.

Graphical abstract: Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase

Supplementary files

Article information

Article type
Communication
Submitted
11 Jul 2005
Accepted
13 Oct 2005
First published
24 Nov 2005

Chem. Commun., 2006, 317-319

Formation of [(L)Ni(μ2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase

P. A. Stenson, A. Marin-Becerra, C. Wilson, A. J. Blake, J. McMaster and M. Schröder, Chem. Commun., 2006, 317 DOI: 10.1039/B509798C

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