Issue 23, 2005
From the journal:

Organic & Biomolecular Chemistry

On the reaction of diphenylketene with isocyanides

Jeremy Robertson,*a   Stephen J. Bella  and  Alexander Krivokapica  

* Corresponding authors

a Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK
E-mail: jeremy.robertson@chem.ox.ac.uk

Abstract

The products obtained from the reaction of diphenylketene with a variety of isocyanides are shown to depend heavily on the concentration of diphenylketene; a high concentration results in the precedented dioxolane derivatives, at much lower concentrations the reactions follow an alternative course and polycyclic β-lactams are generated by a cascade of formal pericyclic reactions.

Graphical abstract: On the reaction of diphenylketene with isocyanides

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Article information

DOI
https://doi.org/10.1039/B512826A
Article type
Paper
Submitted
13 Sep 2005
Accepted
06 Oct 2005
First published
25 Oct 2005

Org. Biomol. Chem., 2005,3, 4246-4251

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On the reaction of diphenylketene with isocyanides

J. Robertson, S. J. Bell and A. Krivokapic, Org. Biomol. Chem., 2005, 3, 4246 DOI: 10.1039/B512826A

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