Issue 22, 2005

A new route to 2-C- and 4-C-branched sugars by palladium–indium bromide-mediated carbonyl allylation

Abstract

Palladium-catalysed carbonyl allylations can be effectively applied to the regio- and diastereoselective synthesis of 2-C- and 4-C-branched sugars from allylic esters or carbonates via the formation of π-allylpalladium(II) intermediates and their reductive transmetalation with indium(I) bromide.

Graphical abstract: A new route to 2-C- and 4-C-branched sugars by palladium–indium bromide-mediated carbonyl allylation

Article information

Article type
Paper
Submitted
01 Aug 2005
Accepted
06 Sep 2005
First published
05 Oct 2005

Org. Biomol. Chem., 2005,3, 4089-4094

A new route to 2-C- and 4-C-branched sugars by palladium–indium bromide-mediated carbonyl allylation

S. Norsikian and A. Lubineau, Org. Biomol. Chem., 2005, 3, 4089 DOI: 10.1039/B510811J

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