Issue 23, 2005

Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids

Abstract

In this perspective we give an overview of enantioselective C–H activation at allylic sites by means of rhodium(II)-stabilized donor–acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis.

Graphical abstract: Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids

Article information

Article type
Perspective
Submitted
05 Jul 2005
First published
31 Oct 2005

Org. Biomol. Chem., 2005,3, 4176-4187

Catalytic and enantioselective allylic C–H activation with donor–acceptor-substituted carbenoids

H. M. L. Davies and J. Nikolai, Org. Biomol. Chem., 2005, 3, 4176 DOI: 10.1039/B509425A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements