Issue 12, 2005
From the journal:

Organic & Biomolecular Chemistry

Diastereoselective reductive imino-aldol reaction of α-imino esters promoted by titanium tetraiodide: synthesis of α,β-diamino esters

Makoto Shimizu,*a   Koji Inayoshia  and  Tetsuya Saharaa  

* Corresponding authors

a Department of Chemistry for Materials, Mie University, Tsu, Mie, Japan
E-mail: mshimizu@chem.mie-u.ac.jp
Fax: +81 59 231 9413

Abstract

Under the influence of titanium tetraiodide reductive imino-aldol reaction of the N-tosylimine derived from ethyl glyoxylate proceeded with aldimines to give α,β-diamino esters in good yields in a highly diastereoselective manner.

Graphical abstract: Diastereoselective reductive imino-aldol reaction of α-imino esters promoted by titanium tetraiodide: synthesis of α,β-diamino esters

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Article information

DOI
https://doi.org/10.1039/B505335H
Article type
Communication
Submitted
18 Apr 2005
Accepted
06 May 2005
First published
18 May 2005

Org. Biomol. Chem., 2005,3, 2237-2238

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Diastereoselective reductive imino-aldol reaction of α-imino esters promoted by titanium tetraiodide: synthesis of α,β-diamino esters

M. Shimizu, K. Inayoshi and T. Sahara, Org. Biomol. Chem., 2005, 3, 2237 DOI: 10.1039/B505335H

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