Issue 8, 2005
From the journal:

Organic & Biomolecular Chemistry

Polycyclic compounds from aminopolyols and α-dicarbonyls: structure and application in the synthesis of exoditopic ligands

Giovanni B. Giovenzana,*a   Giovanni Palmisano,*b   Erika Del Grosso,a   Lorella Giovannelli,a   Andrea Penonib  and  Tullio Pilatic  

* Corresponding authors

a Dipartimento di Scienze Chimiche Alimentari Farmaceutiche Farmacologiche, Via Bovio 6, Novara, Italy
E-mail: giovenza@pharm.unipmn.it

b Dipartimento di Scienze Chimiche e Ambientali, Via Valleggio 11, Como, Italy

c CNR-Istituto di Scienze e Tecnologie Molecolari, Via Golgi 19, Milano, Italy

Abstract

The structure and stereochemistry of the crystalline 2 : 2 condensation product (“glytham”) of glyoxal and tris(hydroxymethyl)aminomethane was conclusively determined by X-ray diffractometric analysis. The singular disposition of the heteroatoms suggests the employment of glytham as starting material for the synthesis of ditopic ligands for metal ions. Some derivatives of glytham were prepared and their binding properties towards alkaline metal ions were preliminarily investigated by ESI-MS and NMR.

Graphical abstract: Polycyclic compounds from aminopolyols and α-dicarbonyls: structure and application in the synthesis of exoditopic ligands

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Article information

DOI
https://doi.org/10.1039/B500580A
Article type
Paper
Submitted
13 Jan 2005
Accepted
18 Feb 2005
First published
15 Mar 2005

Org. Biomol. Chem., 2005,3, 1489-1494

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Polycyclic compounds from aminopolyols and α-dicarbonyls: structure and application in the synthesis of exoditopic ligands

G. B. Giovenzana, G. Palmisano, E. Del Grosso, L. Giovannelli, A. Penoni and T. Pilati, Org. Biomol. Chem., 2005, 3, 1489 DOI: 10.1039/B500580A

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