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Issue 3, 2005
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Aggregation in solution of neutral half-sandwich Ru(II) precatalysts for transfer hydrogenation

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Abstract

Diffusion NMR measurements and ONIOM (B3PW91:UFF) calculations show that amino amidate and acidate half-sandwich Ru(II) precatalysts for transfer hydrogenation have a remarkable tendency to form dimers and even larger aggregates in several solvents, including isopropanol, that is, the solvent used in the catalysis reaction.

Graphical abstract: Aggregation in solution of neutral half-sandwich Ru(ii) precatalysts for transfer hydrogenation

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Publication details

The article was received on 07 Oct 2004, accepted on 16 Nov 2004 and first published on 21 Jan 2005


Article type: Letter
DOI: 10.1039/B415560B
Citation: New J. Chem., 2005,29, 430-433

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    Aggregation in solution of neutral half-sandwich Ru(II) precatalysts for transfer hydrogenation

    D. Zuccaccia, E. Clot and A. Macchioni, New J. Chem., 2005, 29, 430
    DOI: 10.1039/B415560B

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