Issue 10, 2005
From the journal:

New Journal of Chemistry

Novel redox-fluorescence switch based on a triad containing tetrathiafulvalene and pyrene units with tunable monomer and excimer emissions

Xunwen Xiao,ab   Wei Xu,*a   Deqing Zhang,a   Hai Xu,ab   Lei Liuab  and  Daoben Zhu*a  

* Corresponding authors

a Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China
E-mail: wxu@iccas.ac.cn
Fax: 86 10 62569349
Tel: 86 10 62639355

b Graduate School of Chinese Academy of Sciences, Beijing, China

Abstract

The ratio of monomer and excimer emissions of a triad 1 with tetrathiafulvalene (TTF) and pyrene units could be reversibly modulated by the different oxidation states of the TTF unit. The working mechanism of this new fluorescence switch was demonstrated to be the collective result of the tunable photoinduced electron transfer and resonance energy transfer processes.

Graphical abstract: Novel redox-fluorescence switch based on a triad containing tetrathiafulvalene and pyrene units with tunable monomer and excimer emissions

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Article information

DOI
https://doi.org/10.1039/B507488F
Article type
Paper
Submitted
27 May 2005
Accepted
09 Aug 2005
First published
30 Aug 2005

New J. Chem., 2005,29, 1291-1294

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Novel redox-fluorescence switch based on a triad containing tetrathiafulvalene and pyrene units with tunable monomer and excimer emissions

X. Xiao, W. Xu, D. Zhang, H. Xu, L. Liu and D. Zhu, New J. Chem., 2005, 29, 1291 DOI: 10.1039/B507488F

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