Issue 26, 2005
From the journal:

Journal of Materials Chemistry

Acetylenic dithiafulvene derived donor–π–acceptor dyads: synthesis, electrochemistry and non-linear optical properties†

Mogens Brøndsted Nielsen,*a   Jan Conrad Petersen,b   Niels Thorup,c   Mikkel Jessing,a   Asbjørn Sune Andersson,a   Anne Sofie Jepsen,d   Jean-Paul Gisselbrecht,e   Corinne Boudone  and  Maurice Grosse  

* Corresponding authors

a Department of Chemistry, University of Copenhagen, DK-2100 Copenhagen Ø, Denmark
E-mail: mbn@kiku.dk

b Danish Institute of Fundamental Metrology, Bldg. 307, Matematiktorvet, DK-2800 Lyngby, Denmark

c Department of Chemistry, Technical University of Denmark, DK-2800 Lyngby, Denmark

d Department of Chemistry, University of Southern Denmark, Campusvej 55, DK-5230 Odense M, Denmark

e Laboratoire d'Electrochimie et de Chimie Physique du Corps Solide, UMR 7512, CNRS, Université Louis Pasteur, F-67000 Strasbourg, France

Abstract

A selection of donor–acceptor chromophores containing the redox-active dithiafulvene unit about acetylenic and aryl scaffolds has been synthesised. The molecules were studied for their optical, redox and structural properties. Moreover, third-order non-linear optical properties were investigated as a function of molecular structure.

Graphical abstract: Acetylenic dithiafulvene derived donor–π–acceptor dyads: synthesis, electrochemistry and non-linear optical properties

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Article information

DOI
https://doi.org/10.1039/B504124D
Article type
Paper
Submitted
21 Mar 2005
Accepted
11 May 2005
First published
27 May 2005

J. Mater. Chem., 2005,15, 2599-2605

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Acetylenic dithiafulvene derived donor–π–acceptor dyads: synthesis, electrochemistry and non-linear optical properties

M. B. Nielsen, J. C. Petersen, N. Thorup, M. Jessing, A. S. Andersson, A. S. Jepsen, J. Gisselbrecht, C. Boudon and M. Gross, J. Mater. Chem., 2005, 15, 2599 DOI: 10.1039/B504124D

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