Issue 34, 2005
From the journal:

Journal of Materials Chemistry

Development of metallic crystals composed of single-component molecules

Akiko Kobayashi,a   Biao Zhoua  and  Hayao Kobayashib  

a Research Centre for Spectrochemistry, Graduate School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
E-mail: akiko@chem.s.u-tokyo.ac.jp

b Institute for Molecular Science and CREST, JST, Okazaki 444-8585, Japan
E-mail: hayao@ims.ac.jp

Abstract

The novel nickel complex with the extended TTF dithiolate ligand [Ni(tmdt)2] (tmdt = trimethylenetetrathiafulvalenedithiolate) is the first three-dimensional single-component molecular metal with metallic state down to 0.6 K. The isostructural new molecular conductor [Au(tmdt)2] exhibited an unprecedentedly high-temperature antiferromagnetic transition around 85 K without loss of its high conductivity.

Graphical abstract: Development of metallic crystals composed of single-component molecules

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Article information

DOI
https://doi.org/10.1039/B502603B
Article type
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Submitted
21 Feb 2005
Accepted
26 Apr 2005
First published
18 May 2005

J. Mater. Chem., 2005,15, 3449-3451

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Development of metallic crystals composed of single-component molecules

A. Kobayashi, B. Zhou and H. Kobayashi, J. Mater. Chem., 2005, 15, 3449 DOI: 10.1039/B502603B

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