Induced rectification from self-assembled monolayers of sterically hindered π-bridged chromophores
Abstract
Self-assembled monolayers (SAMs) obtained via the chemisorption of bis-[1-(10-decyl)-4-{2-(4-methoxynaphthalen-1-yl)vinyl}quinolinium]disulfide diiodide (1) on gold-coated highly oriented pyrolytic graphite (HOPG) substrates exhibit asymmetric current–voltage characteristics with rectification ratios of ca. 30 at ±1 V when contacted by PtIr or Au probes. The ratio decreases to ca. 10 at ±1 V for pentanethiolate-coated gold probes, which locate the donor–(π-bridge)–acceptor moiety approximately midway between the electrodes: Au–S–C5H11//D–π–A–C10H20–S–Au. The I–V characteristics are different but the current versus electric field dependence is indistinguishable for both types of