Issue 4, 2005
From the journal:

Journal of Materials Chemistry

A novel soluble poly(fluorenylenevinylene) conjugated polymer: synthesis, characterization and application to optoelectronic devices

Jonas Gruber,*a   Rosamaria W. C. Li,a   Luis Henrique J. M. C. Aguiar,a   Adriano R. V. Benvenho,b   Rudolf Lessmannb  and  Ivo A. Hümmelgen*b  

* Corresponding authors

a Instituto de Química, Universidade de São Paulo, C. P. 26077, 05513-970 São Paulo, SP, Brazil
E-mail: jogruber@iq.usp.br
Fax: +55 11 3815-5579
Tel: +55 11 3091-1103

b Departamento de Física, Universidade Federal do Paraná, C. P. 19044, 81531-990 Curitiba, PR, Brazil
E-mail: iah@fisica.ufpr.br
Fax: +55 41 361-3418
Tel: +55 41 361-3645

Abstract

We report the synthesis and characterization of poly(9,9-dioctyl-1,4-fluorenylenevinylene), PDO14FV. This polymer is a novel poly(arylenevinylene) with fluorene units and long chain substituents that ensure solubility in organic solvents. PDO14FV presents green photoluminescence and yellow–green electroluminescence. The estimated ionization potential of PDO14FV is 5.3 eV and its estimated electroaffinity 2.5 eV. Organic light-emitting diodes based on PDO14FV were constructed, showing electroluminescent intensity onset at ca. 6 V.

Graphical abstract: A novel soluble poly(fluorenylenevinylene) conjugated polymer: synthesis, characterization and application to optoelectronic devices

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Article information

DOI
https://doi.org/10.1039/B411063C
Article type
Paper
Submitted
20 Jul 2004
Accepted
07 Oct 2004
First published
15 Nov 2004

J. Mater. Chem., 2005,15, 517-522

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A novel soluble poly(fluorenylenevinylene) conjugated polymer: synthesis, characterization and application to optoelectronic devices

J. Gruber, R. W. C. Li, L. H. J. M. C. Aguiar, A. R. V. Benvenho, R. Lessmann and I. A. Hümmelgen, J. Mater. Chem., 2005, 15, 517 DOI: 10.1039/B411063C

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