Issue 13, 2005
From the journal:

Dalton Transactions

Stabilising small clusters: synthesis and characterisation of thermolabile [Gd4F7(15-crown-5)4][AsF6]5·6SO2

Glen B. Deacon,a   David J. Evans,a   Peter C. Junk,*a   Enno Lork,b   Rüdiger Mews*b  and  Boris Žemvac  

* Corresponding authors

a School of Chemistry, Monash University, Victoria, Australia
E-mail: Peter.Junk@sci.monash.edu.au
Fax: 61 3 9905 4597
Tel: 61 3 9905 4570

b Institute für Anorganische und Physikalische Chemie der Universitiät Bremen, Leobener Straße NW2, Postfach 3300440, Bremen, Germany
E-mail: mews@chemie.uni-bremen.de

c Department of Inorganic Chemistry, Jožef Stefan Institute, Jamova 39, Ljubljana, Slovenia

Abstract

Addition of 15-crown-5 to [GdF(AsF6)2], both dissolved in liquid SO2, and crystallisation at −30 °C has led to the isolation of the tetranuclear ionic complex [Gd4F7(15-crown-5)4][AsF6]5·6SO2 which is stable up to −10 °C where SO2 loss leads to loss of crystallinity.

Graphical abstract: Stabilising small clusters: synthesis and characterisation of thermolabile [Gd4F7(15-crown-5)4][AsF6]5·6SO2

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Article information

DOI
https://doi.org/10.1039/B504819B
Article type
Communication
Submitted
06 Apr 2005
Accepted
19 May 2005
First published
31 May 2005

Dalton Trans., 2005, 2237-2238

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Stabilising small clusters: synthesis and characterisation of thermolabile [Gd4F7(15-crown-5)4][AsF6]5·6SO2

G. B. Deacon, D. J. Evans, P. C. Junk, E. Lork, R. Mews and B. Žemva, Dalton Trans., 2005, 2237 DOI: 10.1039/B504819B

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