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Issue 10, 2005
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Selection of the cis and trans phosph(III)azane macrocycles [{P(µ-NtBu)}2(1-Y-2-NH-C6H4)]2 (Y = O, S)

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The 1 : 1 reactions of [ClP(µ-NtBu)]2 with the difunctional aromatic amines 1,2-1-YH-2-NH2-C6H4 in the presence of Et3N give the dimeric phosph(III)azane macrocycles [{P(µ-NtBu)2(1-Y-2-HN-C6H4)]2, predominantly as the cis isomer in the case of Y = O (1·cis) and as the trans isomer for Y = S (2·trans). Model M.O. calculations suggest that the selection of the cis and trans isomers is not thermodynamically controlled. The alternative isomers 1·trans and 2·cis are generated exclusively by the deprotonation of the model intermediates [(1-Y-2-NH2-C6H4)P(µ-NtBu)]2 [Y = O (3), S (4)] with nBuLi followed by cyclisation with [ClP(µ-NtBu)]2. The solid-state structures of 1·cis/trans (50 : 50), 2·cis, 3 and 4 are reported.

Graphical abstract: Selection of the cis and trans phosph(iii)azane macrocycles [{P(µ-NtBu)}2(1-Y-2-NH-C6H4)]2 (Y = O, S)

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Publication details

The article was received on 14 Feb 2005, accepted on 22 Mar 2005 and first published on 13 Apr 2005

Article type: Paper
DOI: 10.1039/B502200B
Citation: Dalton Trans., 2005,0, 1764-1773

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    Selection of the cis and trans phosph(III)azane macrocycles [{P(µ-NtBu)}2(1-Y-2-NH-C6H4)]2 (Y = O, S)

    F. García, J. M. Goodman, R. A. Kowenicki, M. McPartlin, L. Riera, M. A. Silva, A. Wirsing and D. S. Wright, Dalton Trans., 2005, 0, 1764
    DOI: 10.1039/B502200B

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