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Issue 1, 2005
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Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore

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Abstract

Reaction of 1-hydrazinophthalazine with chloroacetyl chloride yields 3-chloromethyl-1,2,4-triazolo-phthalazine. Reaction of this product with the tris tert-butyl ester of DO3A yields a triazolophthalazine appended macrocycle. Hydrolysis and complexation with lanthanide ions gives access to a series of lanthanide complexes (Ln = Nd, Eu, Yb, Er); these are all luminescent and exhibit sensitisation of the lanthanide centre by the chromophore.

Graphical abstract: Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore

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Publication details

The article was received on 24 Aug 2004, accepted on 29 Oct 2004 and first published on 22 Nov 2004


Article type: Paper
DOI: 10.1039/B413005G
Citation: Dalton Trans., 2005,0, 146-149

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    Synthesis and luminescence properties of lanthanide complexes incorporating a hydralazine-derived chromophore

    B. P. Burton-Pye, S. L. Heath and S. Faulkner, Dalton Trans., 2005, 0, 146
    DOI: 10.1039/B413005G

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