Supramolecular isomerism within three-dimensional 3-connected nets: unusual synthesis and characterization of trimorphic copper(i) 3,5-dimethyl-1,2,4-triazolate†
Abstract
Solvothermal treatments of 2d, a
= 14.0247(5), c
= 5.2884(4)
Å) and orthorhombic phase 3
(Iba2, a
= 8.0423(7), b
= 11.5310(10), c
= 17.3505(16)
Å), respectively. The three isomers also displayed distinct physical properties related to their different supramolecular structures.