Issue 18, 2005
From the journal:

Dalton Transactions

Redox-active dirhodium(ii,ii) species covalently entrapped into a methylmethacrylate backbone†

Sandra Lo Schiavo,*a   Placido Mineo,b   Giuseppe Tresoldi,a   Paola Cardianoa  and  Pasquale Piraino*a  

* Corresponding authors

a Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Salita Sperone n. 31, Vil. S. Agata, Messina, Italy
E-mail: loschiavo@chem.unime.it
Fax: 39 90 393756
Tel: 39 90 6765721

b Consiglio Nazionale delle Ricerche, Istituto di Chimica e Tecnologia dei Polimeri c/o Dipartimento di Scienze Chimiche, Università degli Studi di Catania, Viale A. Doria 6, Catania, Italy
E-mail: gmineo@dipchi.unict.it
Fax: 39 95 221541
Tel: 39 95 7385033

Abstract

A novel class of polymers was obtained by insertion of dirhodium(II,II) metal systems into a methacrylate backbone; the synthesis was realized by free radical polymerization of an appropriate methacrylate-functionalized dirhodium polymer precursor, namely [Rh2(form)2(MA-COO)2] (form = N,N′-di-p-tolylformamidinate) (MA-COO = 2-(methacroyloxy)ethyl-phthalate), with methylmethacrylate (MMA); the new copolymers, in solution, show reversible CO-absorption, connected to the axial reactivity of dirhodium(II,II) species.

Graphical abstract: Redox-active dirhodium(ii,ii) species covalently entrapped into a methylmethacrylate backbone

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Article information

DOI
https://doi.org/10.1039/B509281G
Article type
Communication
Submitted
05 Jul 2005
Accepted
20 Jul 2005
First published
01 Aug 2005

Dalton Trans., 2005, 2979-2981

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Redox-active dirhodium(II,II) species covalently entrapped into a methylmethacrylate backbone

S. Lo Schiavo, P. Mineo, G. Tresoldi, P. Cardiano and P. Piraino, Dalton Trans., 2005, 2979 DOI: 10.1039/B509281G

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