Two-dimensional carboxylate bridged network of europium(iii)–transition metal(ii) glutarate compounds

Abstract

Four new heterometallic glutarate coordination polymers, [Eu₂M(H₂O)₄][O₂C(CH₂)₃CO₂]₄·2H₂O (M = Mn (1), Fe (2), Co (3) and Ni (4)) have been obtained under hydrothermal synthesis. The single-crystal X-ray diffraction analyses showed that they have two-dimensional frameworks based on the linear polyhedral chains consisting of two nine-coordinated Eu(III)O₉ and a six-coordinated M(II)O₆. These 1-D MO₆–Eu₂O₁₆ chains are cross-linked by glutarate ligands as an interchain pillared architecture, whose conformations vary depending upon the transition metals. The magnetic behavior of the compounds show a weak antiferromagnetic interaction, in which shielding of the 4f electrons by the outer shell electrons effectively precludes significant coupling interactions between the Eu-4f electrons and transition metal (M)-3d electrons.