Issue 9, 2005
From the journal:

Dalton Transactions

Strong enhancement of second-harmonic generation (SHG) response through multi-chiral centers and metal-coordination†

Qiong Ye,a   Yu-Zhi Tang,a   Xi-Sen Wanga  and  Ren-Gen Xiong*a  

* Corresponding authors

a Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, P. R. China
E-mail: xiongrg@netra.nju.edu.cn
Fax: (+86)-25-83317761

Abstract

The hydrothermal reaction of CdCl2 with L (L = trans-2,3-dihydro-2-(4′-pyridyl)-3-(3″-cyanophenyl)benzo[e]indole) in the presence of NaN3 and water offers a novel route to [Cd(L–N3)2(H2O)2]n (1), a 1D infinite molecular box with approximate dimensions 10.37 × 6.64 Å; 1 is shown to display a very strong SHG response that is 80 times that observed for urea.

Graphical abstract: Strong enhancement of second-harmonic generation (SHG) response through multi-chiral centers and metal-coordination

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Article information

DOI
https://doi.org/10.1039/B503039K
Article type
Communication
Submitted
02 Mar 2005
Accepted
21 Mar 2005
First published
11 Apr 2005

Dalton Trans., 2005, 1570-1573

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Strong enhancement of second-harmonic generation (SHG) response through multi-chiral centers and metal-coordination

Q. Ye, Y. Tang, X. Wang and R. Xiong, Dalton Trans., 2005, 1570 DOI: 10.1039/B503039K

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