Issue 68, 2005
From the journal:

CrystEngComm

Supramolecular self-assembly of tin(iv) porphyrin channels stabilizing single-file chains of water molecules†

Hee-Joon Kim,*a   Hwa Jin Jo,a   Jaheon Kim,b   Soo-Young Kim,c   Dongwoo Kimc  and  Kimoon Kimc  

* Corresponding authors

a Department of Applied Chemistry, Kumoh National Institute of Technology, 1 Yangho-dong, Gumi 730-701, Republic of Korea
E-mail: hjk@kumoh.ac.kr

b Department of Chemistry and CAMDRC, Soongsil University, Seoul 156-743, Republic of Korea

c National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea

Abstract

The supramolecular assembly of tin(IV) porphyrin equipped with six pyridyl groups, trans-diisonicotinate[meso-tetrakis(4-pyridyl)porphyrinato]tin(IV), generates a uniform channel lined with the pyridyl groups, in which the lattice water molecules are ordered into a single-file chain by hydrogen bonding between neighboring water molecules along the chain as well as hydrogen bonding between water molecules and the pyridyl lining of the channel.

Graphical abstract: Supramolecular self-assembly of tin(iv) porphyrin channels stabilizing single-file chains of water molecules

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Article information

DOI
https://doi.org/10.1039/B504841A
Article type
Communication
Submitted
06 Apr 2005
Accepted
17 Jun 2005
First published
22 Jun 2005

CrystEngComm, 2005,7, 417-420

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Supramolecular self-assembly of tin(IV) porphyrin channels stabilizing single-file chains of water molecules

H. Kim, H. J. Jo, J. Kim, S. Kim, D. Kim and K. Kim, CrystEngComm, 2005, 7, 417 DOI: 10.1039/B504841A

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