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Issue 37, 2005
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The highest water exchange rate ever measured for a Gd(III) chelate

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Abstract

The complex [Gd(L)(H2O)]3− (H6L = N,N′-bis(6-carboxy-2-pyridylmethyl)ethylenediamine-N,N′-methylenephosphonic acid) displays the highest water exchange rate ever measured for a Gd(III) chelate (k298ex = 8.8 × 108 s−1), which is attributed to the flexibility of the metal coordination environment.

Graphical abstract: The highest water exchange rate ever measured for a Gd(iii) chelate

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Publication details

The article was received on 09 Jun 2005, accepted on 01 Aug 2005 and first published on 26 Aug 2005


Article type: Communication
DOI: 10.1039/B508180G
Citation: Chem. Commun., 2005,0, 4729-4731
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    The highest water exchange rate ever measured for a Gd(III) chelate

    M. Mato-Iglesias, C. Platas-Iglesias, K. Djanashvili, J. A. Peters, É. Tóth, E. Balogh, R. N. Muller, L. Vander Elst, A. de Blas and T. Rodríguez-Blas, Chem. Commun., 2005, 0, 4729
    DOI: 10.1039/B508180G

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