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Issue 26, 2005
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Unprecedented, fully recyclable, solid-supported reagent for the kinetic resolution of racemic amines through enantioselective N-acetylation

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Abstract

The high-yielding synthesis and application of the first polymer supported reagent for the kinetic resolution (KR) of amines through enantioselective acetylation is described; this new supported chiral reagent allows the KR of primary amines with excellent selectivities at room temperature; moreover, this supported approach is highly efficient as the Merrifield-supported chiral scaffold can be quantitatively recovered and recycled.

Graphical abstract: Unprecedented, fully recyclable, solid-supported reagent for the kinetic resolution of racemic amines through enantioselective N-acetylation

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Publication details

The article was received on 24 Mar 2005, accepted on 03 May 2005 and first published on 01 Jun 2005


Article type: Communication
DOI: 10.1039/B504200C
Chem. Commun., 2005, 3310-3312

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    Unprecedented, fully recyclable, solid-supported reagent for the kinetic resolution of racemic amines through enantioselective N-acetylation

    S. Arseniyadis, P. V. Subhash, A. Valleix, A. Wagner and C. Mioskowski, Chem. Commun., 2005, 3310
    DOI: 10.1039/B504200C

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