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Issue 11, 2005
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Catalytic asymmetric synthesis of enantiopure isoprenoid building blocks: application in the synthesis of apple leafminer pheromones

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Abstract

The first catalytic asymmetric procedure capable of preparing all 4 diastereoisomers (ee > 99%, de > 98%) of a versatile saturated isoprenoid building block was developed and the value of this new method was demonstrated in its application to the concise total synthesis of two pheromones.

Graphical abstract: Catalytic asymmetric synthesis of enantiopure isoprenoid building blocks: application in the synthesis of apple leafminer pheromones

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Supplementary files

Article information


Submitted
23 Dec 2004
Accepted
27 Jan 2005
First published
09 Feb 2005

Chem. Commun., 2005, 1387-1389
Article type
Communication

Catalytic asymmetric synthesis of enantiopure isoprenoid building blocks: application in the synthesis of apple leafminer pheromones

R. P. van Summeren, S. J. W. Reijmer, B. L. Feringa and A. J. Minnaard, Chem. Commun., 2005, 1387
DOI: 10.1039/B419268K

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