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Issue 11, 2005
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The effect of spacer chain length on ion binding to bidentate α,ω-diamines: Contrasting ordering for H+ and Li+ ion affinities

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Abstract

Electrospray ionisation mass spectrometry studies and quantum chemical calculations indicate that bidentate ligation of Li+ ion to the diamines leads to symmetric bridging and exhibits contrasting relative affinity orderings compared to that of proton for α,ω-diamines.

Graphical abstract: The effect of spacer chain length on ion binding to bidentate α,ω-diamines: Contrasting ordering for H+ and Li+ ion affinities

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Article information


Submitted
21 Sep 2004
Accepted
03 Dec 2004
First published
26 Jan 2005

Chem. Commun., 2005, 1420-1422
Article type
Communication

The effect of spacer chain length on ion binding to bidentate α,ω-diamines: Contrasting ordering for H+ and Li+ ion affinities

M. K. Kumar, J. S. Rao, S. Prabhakar, M. Vairamani and G. N. Sastry, Chem. Commun., 2005, 1420
DOI: 10.1039/B414426K

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