Enantioselective hydrogenation of polar substrates in inverted supercritical CO2/aqueous biphasic media

Katja Burgemeister; Giancarlo Franciò; Herbert Hugl; Walter Leitner

doi:10.1039/B512110H

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Enantioselective hydrogenation of polar substrates in inverted supercritical CO₂/aqueous biphasic media†

Katja Burgemeister,^a Giancarlo Franciò,^a Herbert Hugl^c and Walter Leitner*^ab

Author affiliations

* Corresponding authors

^a Institut für Technische und Makromolekulare Chemie, RWTH Aachen, Worringerweg 1, Aachen, Germany
E-mail: leitner@itmc.rwth-aachen.de
Fax: +49-(0)241-8022177
Tel: +49-(0)241-8026480

^b Max-Planck-Institut für Kohlenforschung, Mülheim an der Ruhr, Germany

^c LANXESS Deutschland GmbH, Leverkusen, Germany

Abstract

An inverted supercritical CO₂/aqueous biphasic catalytic system allows highly enantioselective hydrogenation of polar water-soluble substrates and efficient recycling of the CO₂-philic catalysts.

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Article information

DOI: https://doi.org/10.1039/B512110H
Article type: Communication
Submitted: 25 Aug 2005
Accepted: 05 Oct 2005
First published: 08 Nov 2005

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Chem. Commun., 2005, 6026-6028

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Enantioselective hydrogenation of polar substrates in inverted supercritical CO₂/aqueous biphasic media

K. Burgemeister, G. Franciò, H. Hugl and W. Leitner, Chem. Commun., 2005, 6026 DOI: 10.1039/B512110H

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