Issue 41, 2005
From the journal:

Chemical Communications

Generation effects on the microstructure and product distribution in ethylenepolymerization promoted by dendritic nickel catalysts†

José M. Benito,a   Ernesto de Jesús,*a   F. Javier de la Mata,a   Juan C. Flores*a  and  Rafael Gómeza  

* Corresponding authors

a Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, Alcalá de Henares, Madrid, Spain
E-mail: ernesto.dejesus@uah.es, juanc.flores@uah.es
Fax: +34 91 885 4683

Abstract

Carbosilane dendrimers Gn–[(ONNMe2)NiBr2]m, containing up to sixteen terminal pyridylimine nickel complexes, have been studied as catalysts for polymerization of ethylene; the microstructure and the oligomer/polymer distribution are significantly affected by the generation of the dendritic precursor.

Graphical abstract: Generation effects on the microstructure and product distribution in ethylene polymerization promoted by dendritic nickel catalysts

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Article information

DOI
https://doi.org/10.1039/B511379M
Article type
Communication
Submitted
09 Aug 2005
Accepted
05 Sep 2005
First published
22 Sep 2005

Chem. Commun., 2005, 5217-5219

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Generation effects on the microstructure and product distribution in ethylene polymerization promoted by dendritic nickel catalysts

J. M. Benito, E. de Jesús, F. J. de la Mata, J. C. Flores and R. Gómez, Chem. Commun., 2005, 5217 DOI: 10.1039/B511379M

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