Issue 43, 2005

A unique example of a 36 tessellated 2-D net based on a tri-nuclear zinc(ii)-1,4-benzenedicarboxylate framework

Abstract

Reaction of Zn(NO3)2 and 1,4-benzenedicarboxylic acid (1,4-H2BDC) at 100 °C for 24 hours in a pressure tube yielded on cooling {[Zn3(1,4-BDC)3(DEF)2]·DEF} (DEF = diethylformamide) incorporating planar six-connected centres to give a unique 36 tessellated 2-D framework polymer.

Graphical abstract: A unique example of a 36 tessellated 2-D net based on a tri-nuclear zinc(ii)-1,4-benzenedicarboxylate framework

Supplementary files

Article information

Article type
Communication
Submitted
14 Jul 2005
Accepted
06 Sep 2005
First published
03 Oct 2005

Chem. Commun., 2005, 5435-5437

A unique example of a 36 tessellated 2-D net based on a tri-nuclear zinc(II)-1,4-benzenedicarboxylate framework

C. A. Williams, A. J. Blake, P. Hubberstey and M. Schröder, Chem. Commun., 2005, 5435 DOI: 10.1039/B509929C

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