Issue 41, 2005
From the journal:

Chemical Communications

Unique self-assembled 2D metal-tetrazolate networks: crystal structure and magnetic properties of [M(pmtz)2] (M = Co(ii) and Fe(ii); Hpmtz = 5-(pyrimidyl)tetrazole)†

Antonio Rodríguez,a   Raikko Kivekäsb  and  Enrique Colacio*a  

* Corresponding authors

a Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, E-18071 Granada, Spain
E-mail: ecolacio@ugr.es, antonio5@ugr.es
Fax: +34 9582 48526
Tel: +34 9582 43236

b Department of Chemistry, PO Box55, FI-00014 University of Helsinki, Helsinki, Finland
E-mail: raikkok@saunalahti.fi
Tel: +358 40 9007496

Abstract

The title compounds, which have been prepared from M(II) salts (M = Co and Fe) and 5-(pyrimidyl)tetrazole under hydrothermal conditions, are isomorphous and exhibit a 2D square-grid-like structure; the cobalt complex is a spin-canted antiferromagnet with Tc = 15 K.

Graphical abstract: Unique self-assembled 2D metal-tetrazolate networks: crystal structure and magnetic properties of [M(pmtz)2] (M = Co(ii) and Fe(ii); Hpmtz = 5-(pyrimidyl)tetrazole)

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Article information

DOI
https://doi.org/10.1039/B509069E
Article type
Communication
Submitted
29 Jun 2005
Accepted
02 Sep 2005
First published
22 Sep 2005

Chem. Commun., 2005, 5228-5230

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Unique self-assembled 2D metal-tetrazolate networks: crystal structure and magnetic properties of [M(pmtz)2] (M = Co(II) and Fe(II); Hpmtz = 5-(pyrimidyl)tetrazole)

A. Rodríguez, R. Kivekäs and E. Colacio, Chem. Commun., 2005, 5228 DOI: 10.1039/B509069E

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