Issue 40, 2005
From the journal:

Chemical Communications

Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems†

Xikui Fang,a   Travis M. Anderson,a   Yu Houa  and  Craig L. Hill*a  

* Corresponding authors

a Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, USA
E-mail: chill@emory.edu
Fax: +1 404-727-6076
Tel: +1 404-727-6611

Abstract

Pure enantiomers of a polytungstate cluster [(α-P2W16O59)Zr2(μ3-O)(mal)]218− (mal = malate) have been obtained and their conversion to meso diastereomers was observed by 31P NMR.

Graphical abstract: Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems

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Article information

DOI
https://doi.org/10.1039/B508468G
Article type
Communication
Submitted
16 Jun 2005
Accepted
23 Aug 2005
First published
16 Sep 2005

Chem. Commun., 2005, 5044-5046

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Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems

X. Fang, T. M. Anderson, Y. Hou and C. L. Hill, Chem. Commun., 2005, 5044 DOI: 10.1039/B508468G

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